Ibogaine is a naturally occurring psychoactive substance with psychedelic and dissociative properties being studied by Johns Hopkins University for its remarkable capacity to reduce addictive behavior or break addiction following only a single session.

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I've heard people talk about Salvia Divinorum's addition reduction abilities. Although you can find extreme videos of people taking it online, it is short lasting, cheap (if it were legal), and much safer, with less likelihood of medical complications.